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Beilstein J. Org. Chem. 2013, 9, 1572–1577, doi:10.3762/bjoc.9.179
Graphical Abstract
Scheme 1: Imidate hydrochloride synthesis discovered by Pinner and Klein [1,2].
Scheme 2: Mechanism of the Pinner reaction.
Scheme 3: Transformations of imidate hydrochlorides.
Scheme 4: Reaction used for optimizations.
Scheme 5: Plausible mechanism of the Lewis acid-promoted Pinner reaction.
Scheme 6: Synthesis of monaspilosin.
Scheme 7: Proposed mechanism of the trimethylsilyl triflate-promoted Ritter reaction.